1-Methoxy-4-(methylthio)benzene → 2-(5-Methoxy-2-methylsulfanylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491132

反応式

COc1ccc(SC)cc1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1.[Ir].[Ir]>COc1ccc(SC)c(B2OC(C)(C)C(C)(C)O2)c1

参加物

反応条件

温度: 55 °C

実験手順

Ligand 3f: A mixture of ortho- and meta-borylated products (92 mg, 66% yield, ortho/meta + para = >20); ortho-borylated product 4c was obtained by further purification by GPC (70 mg, 50% yield), white solid (mp. 71-73 oC)

出典と根拠

ORDレコード: ord-2aa42d9e8bac447fb49a48f178396241
出典データセット: Borylation dataset from Roche
DOI: 10.1002/anie.201610041

反応式

参加物

反応物 1

生成物 1

試薬・触媒・溶媒 4

反応条件

実験手順

出典と根拠

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