4-Phenylthioanisole → 4,4,5,5-Tetramethyl-2-(2-methylsulfanyl-5-phenylphenyl)-1,3,2-dioxaborolane

HRID 1491140

反応式

CSc1ccc(-c2ccccc2)cc1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1.[Ir].[Ir]>CSc1ccc(-c2ccccc2)cc1B1OC(C)(C)C(C)(C)O1

参加物

反応条件

温度: 55 °C

実験手順

Ligand 3f: A mixture of ortho- and meta-borylated products (140 mg, 86% yield, ortho/meta + para = >30); ortho-borylated product 4g was obtained by further purification by GPC (128 mg, 79% yield), white solid (mp. 116-118 oC)

出典と根拠

ORDレコード: ord-a2d89378380b4f06b6a03649928343ec
出典データセット: Borylation dataset from Roche
DOI: 10.1002/anie.201610041

反応式

参加物

反応物 1

生成物 1

試薬・触媒・溶媒 4

反応条件

実験手順

出典と根拠

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