3-Methoxythioanisole → 2-(4-Methoxy-2-(methylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491144

反応式

COc1cccc(SC)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1.[Ir].[Ir]>COc1ccc(B2OC(C)(C)C(C)(C)O2)c(SC)c1

参加物

反応条件

温度: 55 °C

実験手順

Ligand 3f: A mixture of ortho- and meta-borylated products (84 mg, 60% yield, ortho/meta + para = >30); ortho-borylated product 4i was obtained by further purification by GPC (71 mg, 51% yield), colorless oil;

出典と根拠

ORDレコード: ord-7487af86acf14633b8eaaa84b7fb2b65
出典データセット: Borylation dataset from Roche
DOI: 10.1002/anie.201610041

反応式

参加物

反応物 1

生成物 1

試薬・触媒・溶媒 4

反応条件

実験手順

出典と根拠

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