Benzene, 1-methyl-3-(methylthio)- → 4,4,5,5-Tetramethyl-2-(4-methyl-2-(methylthio)phenyl)-1,3,2-dioxaborolane
反応式
CSc1cccc(C)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.FC(F)(F)C1COB(c2ccccc2-c2ccc(-c3ccccn3)nc2)O1.[Ir].[Ir]>CSc1cc(C)ccc1B1OC(C)(C)C(C)(C)O1参加物
6
反応物 1
生成物 1
試薬・触媒・溶媒 4
反応条件
- 温度
- 55 °C
実験手順
Ligand 3f: A mixture of ortho- and meta-borylated products (85 mg, 64% yield, ortho/meta + para = >30); ortho-borylated product 4j was obtained by further purification by GPC (76 mg, 58% yield), yellow solid (mp. 58-60 oC)
出典と根拠
- ORDレコード
- ord-af10b59ddcf44a2ea87f0362701426e9
- 出典データセット
- Borylation dataset from Roche
反応ノート
読み込み中…