HCID 15143423、化合物 → HCID 13685437、化合物
反応式
C([O:8][CH2:9][C@H:10]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH3:11])C1C=CC=CC=1>[Pd].C(O)C>[CH2:13]([O:12][C@H:10]([CH3:11])[CH2:9][OH:8])[CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]参加物
4
実験手順
A mixture liquid of the above (R)-1-benzyloxy-2-hexyloxy-propane (25 g),palladium/carbon catalyst (2.0 g) and ethanol (200 ml) was subjected to hydrogenolysis. After completion of the reaction, the catalyst was filtered off, followed by concentrating the mother liquor, and distilling the concentrate under reduced pressure to obtain (R)-2-hexyloxy-1-propanol (b.p. 67°-68° C./4 mmHg) (11.6 g).
後処理
- customAfter completion of the reaction
- filtrationthe catalyst was filtered off
- concentrationby concentrating the mother liquor
- distillationdistilling the
- concentrationconcentrate under reduced pressure
出典と根拠
- ORDレコード
- ord-5d31cdb1a6644ed2a51519e74e855cb6
- 出典データセット
- uspto-grants-1991_06
- 特許番号
- US05021191
反応ノート
読み込み中…