Methacrylic Acid → Triphenyl bismuth (V) methacrylate

HRID 1493115

反応式

HRID 1493115 の反応式
[C:1]1([Bi:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]([OH:25])(=[O:24])[C:21]([CH3:23])=[CH2:22].C(OO)(C)(C)C>C(OCC)C>[C:20]([O-:25])(=[O:24])[C:21]([CH3:23])=[CH2:22].[C:14]1([Bi+2:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[C:20]([O-:25])(=[O:24])[C:21]([CH3:23])=[CH2:22]

参加物

5

反応物 3

HCID 4093Methacrylic AcidHCID 6410tert-Butyl hydroperoxideHCID 11774Triphenylbismuth

生成物 1

HCID 19830615Triphenyl bismuth (V) methacrylate

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

The general method as outlined by V. A. Dodonov, A. V. Gustichin and T. G. Brilkina (Zh. Obsch. Khim 55, 1(73) 1985) was followed for the preparation of this compound. The details of a typical preparation are: Triphenyl bismuthine (4.4 g, 0.01 mol.), methacrylic acid (1.97 g) (0.02 mol), tert-butyl hydroperoxide (1.39 g) were mixed with 20 ml of diethyl ether in a round bottom flask. The contents were stirred overnight (20 hr) at ambient temperature. The volatile matter was then removed in vacuo (0.1 mm Hg) for 5 hr to obtain a solid which was analyzed for its metal content.

後処理

  1. customBrilkina (Zh. Obsch. Khim 55, 1(73) 1985) was followed for the preparation of this compound
  2. customThe details of a typical preparation
  3. customThe volatile matter was then removed in vacuo (0.1 mm Hg) for 5 hr
  4. customto obtain a solid which

出典と根拠

ORDレコード
ord-32d84826fcbb49c1928fcb3e2ecb49a8
出典データセット
uspto-grants-1991_06
特許番号
US05021398

関連ノート

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