トリフェニルビスムチン

Triphenylbismuth

HCID 11774CAS 603-33-8
部分構造検索類似構造を探す

基本情報

標準SMILES
c1cc[c]([Bi]([c]2ccccc2)[c]2ccccc2)cc1
InChIKey
ZHXAZZQXWJJBHA-UHFFFAOYSA-N
分子式
C18H15Bi
平均分子量
440.3 g/mol
単同位体質量
440.09777418

概要

structure given in first source

名称と識別子

優先名称
Triphenylbismuth
IUPAC
triphenylbismuthane
現地名
トリフェニルビスムチン
英語名
Triphenylbismuth
分子式
C18H15Bi
分子量
440.29

名称と別名

Triphenylbismuth603-33-8TriphenylbismuthineTriphenyl bismuthBISMUTHINE, TRIPHENYL-AerotexTrifenylbismutinDTXSID6042498Triphenyl bismuthineNSC-465R18732F41WDTXCID4022498
名称をさらに表示
トリフェニルビスムチントリフェニルビスマス,3Nとりふぇにるびすますトリフェニルビスマス(III)トリフェニルビスムタンTPB(C6H5)3Bitriphenyl-bismuthinTriphenylbismuth,99%Triphenylbismuth,98%
Ph3BiRefChem:191900210-033-4triphenylbismuthaneBismuth triphenylBismuth, triphenyl-MFCD00014064Caswell No. 896

データベース識別子

CAS
603-33-8
PubChem CID
11774
DTXSID
DTXSID6042498
UNII
R18732F41W
EC Number
210-033-4
Nikkaji
J42.067K

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
3
重原子数
19

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure0.000034 [mmHg]
Physical Description · 2 件

CBI

Solid; [Merck Index] White to off-white powder; [Alfa Aesar MSDS]

物理化学的性質

融点
78 · 78-80 °C
沸点
310 °C · 310°C
比重(密度)
1 · 1,585 g/cm3
屈折率
1.704 · 1.7040
闪点
242 °C/14mm · 242°C/14mm
貯蔵温度
Inert atmosphere,Room Temperature

化学的性質

化学的特性white to off-white crystalline powder

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 2.1% (1 of 47) of reports.

Warning

H302 (95.7%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 3 件

Hazard Traits - Bioaccumulation; Environmental Persistence

Bismuthine, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Bismuthine, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Bismuthine, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryMay cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Triphenylantimony.
Hazard Classes and CategoriesAcute Tox. 4 (95.7%)

安全データ

wgk
3
tsca
TSCA listed
rtecs
EB2980000
hs_code
29319090
risk_code
20/21/22
hazard_code
Xn

化学と産業

用途と製造

UsesUsed as a radiopacifying agent in dental resins and medical devices, polymerization catalyst, and in organic synthesis; [Merck Index]
U.S. Production2023: <50,000 lb
Industry UsesOther
General Manufacturing Information · 2 件

All Other Chemical Product and Preparation Manufacturing

Bismuthine, triphenyl-: ACTIVE

応用分野 · 2 件

解説トリフェニルビスムチン,無色の針状結晶．融点78 ℃．快臭を有し，空気に対して安定である．有機溶媒に可溶，水に不溶．有機ビスマス化合物のなかではもっとも安定である．塩酸で分解してベンゼンと三塩化ビスマスとなる．ICl，ICNとの反応で，それぞれ(C6H5)2BiCl，(C6H5)2BiCNを生じる．森北出版「化学辞典（第2版）

使用Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.

調製方法 · 2 件

製造方法Triphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.

純化方法Dissolve it in EtOH, precipitate it with H2O, extract with Et2O, dry and evaporate till the residue crystallises. It has been recrystallised from EtOH and Et2O/EtOH and is a stable compound. [Forward et al. J Chem Soc suppl p121 1949, Pfeiffer et al. Chem Ber 37 4620 1904, Gilman & Yablunky J Am Chem Soc 62 665 1940, UV: Jaffé J Chem Phys 22 1430 1954, Beilstein 4 III 1841.]

上流・下流製品情報

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