Thionyl Chloride → HCID 53915754、化合物

反応式

[CH:1]([C:3]1([C:12]([OH:14])=O)[CH2:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4]1)=[CH2:2].S(Cl)([Cl:17])=O>>[CH:1]([C:3]1([C:12]([Cl:17])=[O:14])[CH2:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4]1)=[CH2:2]

参加物

反応物 2

HCID 24386Thionyl Chloride

HCID 19828700HCID 19828700、化合物

生成物 1

HCID 53915754HCID 53915754、化合物

実験手順

A mixture 2,3-dihydro-2-vinyl-1H-indene-2-carboxylic acid (5.09 g) and thionyl chloride (25 ml) was refluxed for 10 hours. Excess thionyl chloride was distilled off under reduced pressure. The crude product was used as such for the following reaction.

後処理

distillationExcess thionyl chloride was distilled off under reduced pressure
customsuch for the following reaction

出典と根拠

ORDレコード: ord-89f5ee2aa9fd40c395f9ef973cc3e60a
出典データセット: uspto-grants-1991_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05026868

反応ノート

読み込み中…