Hydrochloric Acid → HCID 21226522、化合物

HRID 1496786ノート

反応式

HRID 1496786 の反応式
[Na].[C:2]1([S:16](O)(=O)=O)[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.P(Cl)(Cl)Cl.P(Cl)(Cl)(Cl)(Cl)Cl.C1(S(Cl)(=O)=O)C2C(=CC3C(C=2)=CC=CC=3)C=CC=1.[H-].[Al+3].[Li+].[H-].[H-].[H-].Cl>C1COCC1>[C:2]1([SH:16])[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1

参加物

8

反応物 6

HCID 313Hydrochloric AcidHCID 24387Phosphorus trichlorideHCID 24819Phosphorus pentachlorideHCID 2844471-Anthracenesulfonyl chloride2 回HCID 21226445Aluminium lithium hydrideHCID 86660809Anthracene-1-sulfonic acid sodium salt

生成物 1

HCID 21226522HCID 21226522、化合物

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

The reaction of anthracene (Tokyo chemical industry Co., Ltd) with sulfur trioxide (Tokyo chemical industry Co., Ltd) was conducted in the presence of the piperidine catalyst to synthesize β-anthracenesulfonic acid, followed by a treatment with a sodium hydroxide solution to obtain anthracenesulfonic acid sodium. The obtained anthracenesulfonic acid sodium was allowed to react with phosphorous trichloride and phosphorous pentachloride (Tokyo chemical industry Co., Ltd) in a solvent of phosphorous dichloride (Tokyo chemical industry Co., Ltd) at the temperature of 120° C., thereby obtaining anthracenesulfonyl chloride. In THF, anthracenesulfonyl chloride was allowed to react with lithium aluminum hydride, followed by a treatment with hydrochloric acid to yield anthracene thiol.

出典と根拠

ORDレコード
ord-58507216158e470782b380e10ec13847
出典データセット
uspto-grants-2015_12
特許番号
US09199130B2

反応ノート

読み込み中…