Dimethylformamide → HCID 74949036、化合物
反応式
[C:1]([OH:12])(=O)[CH:2]=[CH:3][CH2:4][CH2:5][CH:6]=[CH:7][CH:8]=[CH:9][CH3:10].CN(C=O)C.S(Cl)([Cl:20])=O>C1(C)C=CC=CC=1>[C:1]([Cl:20])(=[O:12])[CH:2]=[CH:3][CH2:4][CH2:5][CH:6]=[CH:7][CH:8]=[CH:9][CH3:10]参加物
5
反応条件
- 温度
- 5 °C
実験手順
In an atmosphere of nitrogen, a toluene solution of the above-mentioned 2,6,8-decatrienoic acid (7) and DMF (3.7 g, 0.05 mol) were added to a 100 ml capacity flask, followed by cooling to 5° C. Thionyl chloride (11.9 g, 0.10 mol) was added dropwise to this, followed by stirring at 5° C. for 0.5 hour to obtain a toluene solution of 2,6,8-decatrienoic acid chloride (8).
出典と根拠
- ORDレコード
- ord-13750b2ac8ae47199d50fe5ee39b40ce
- 出典データセット
- uspto-grants-2012_07
- 特許番号
- US08217192B2
反応ノート
読み込み中…