Dimethylformamide → HCID 74949036、化合物

HRID 1513548ノート

反応式

HRID 1513548 の反応式
C1(C)C=CC=CC=1.[C:8]([OH:19])(=O)[CH:9]=[CH:10][CH2:11][CH2:12][CH:13]=[CH:14][CH:15]=[CH:16][CH3:17].CN(C=O)C.S(Cl)([Cl:27])=O>C1(C)C=CC=CC=1>[C:8]([Cl:27])(=[O:19])[CH:9]=[CH:10][CH2:11][CH2:12][CH:13]=[CH:14][CH:15]=[CH:16][CH3:17]

参加物

5

反応物 3

HCID 6228DimethylformamideHCID 24386Thionyl ChlorideHCID 86653159HCID 86653159、化合物

生成物 1

HCID 74949036HCID 74949036、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
5 °C

実験手順

In an atmosphere of nitrogen, the 2,6,8-decatrienic acid toluene solution obtained in the above and DMF (3.7 g, 0.05 mol) were added to a 100 ml capacity flask, followed by cooling to 5° C. Thionyl chloride (11.9 g, 0.10 mol) was added dropwise to this and stirring was carried out at 5° C. for 0.5 hour to obtain a toluene solution of 2,6,8-decatrienoic acid chloride.

後処理

  1. additionwere added to a 100 ml capacity flask

出典と根拠

ORDレコード
ord-f8baae808ba9401d91ae0cd6a04dd613
出典データセット
uspto-grants-2012_07
特許番号
US08217192B2

反応ノート

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