4-Methylpyridine → 2-Acetoxy-4-methylpyridine
反応式
[OH:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][N:3]=1.CC1C=CN=CC=1.F[O:17][C:18](=O)[CH3:19]>>[C:18]([O:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][N:3]=1)(=[O:17])[CH3:19]参加物
4
実験手順
As a process for the preparation of 2-hydroxy-4-methylpyridine, a process whereby [iv] 4-methylpyridine is reacted with acetyl hypofluorite at −10° C. to obtain a 2-acetoxy-4-methylpyridine, and thereafter the 2-acetoxy-4-methylpyridine is hydrolyzed to obtain 4-methyl-2-pyridone is reported [Journal of the American Chemical Society, 109, 3789-3790, (1987): Non-Patent Reference 2].
出典と根拠
- ORDレコード
- ord-134324e128ff46398b4c24f101b11fde
- 出典データセット
- uspto-grants-2012_07
- 特許番号
- US08227617B2
反応ノート
読み込み中…