HCID 17954114、化合物 → 460078-00-6
反応式
[N:1]([CH2:4][CH2:5][CH:6]([CH2:12][CH2:13][N:14]=[N+]=[N-])[CH2:7][CH2:8][N:9]=[N+]=[N-])=[N+]=[N-].[H][H]>C(O)C.[Pd]>[NH2:1][CH2:4][CH2:5][CH:6]([CH2:12][CH2:13][NH2:14])[CH2:7][CH2:8][NH2:9]参加物
5
実験手順
Tris(2-azidoethyl)methane (15.06 g, 0.0676 mol), (assuming 100% yield from previous reaction) in ethanol (200 ml) was treated with 10% palladium on charcoal (2 g, 50% water) and hydrogenated for 12 h. The reaction vessel was evacuated every 2 hours to remove nitrogen evolved from the reaction and refilled with hydrogen. A sample was taken for NMR analysis to confirm complete conversion of the triazide to the triamine.
後処理
- customThe reaction vessel was evacuated every 2 hours
- customto remove nitrogen
- customevolved from the reaction
出典と根拠
- ORDレコード
- ord-a555a33cf69948ffbcc053fc5526018e
- 出典データセット
- uspto-grants-2012_07
- 特許番号
- US08231858B2
反応ノート
読み込み中…