Dichloromethane → Copper, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N(21)-,N(22)-,N(23)-,N(24)-]-

HRID 1534971

反応式

HRID 1534971 の反応式
[CH:1]1[CH:2]=[CH:3][C:4]([C:7]2[C:8]3[NH:12][C:11]([C:13]([C:43]4[CH:44]=[CH:45][CH:46]=[CH:47][CH:48]=4)=[C:14]4[CH:42]=[CH:41][C:16](=[C:17]([C:35]5[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=5)[C:18]5[CH:34]=[CH:33][C:20](=[C:21]([C:27]6[CH:28]=[CH:29][CH:30]=[CH:31][CH:32]=6)[C:22]6[CH:23]=[CH:24][C:25]=2[N:26]=6)[N:19]=5)[NH:15]4)=[CH:10][CH:9]=3)=[CH:5][CH:6]=1.O.C([O-])(=O)C.[Cu+2:54].C([O-])(=O)C.C(Cl)Cl>C(Cl)(Cl)Cl.CO>[C:43]1([C:13]2[C:11]3[NH:12][C:8](=[CH:9][CH:10]=3)[C:7]([C:4]3[CH:5]=[CH:6][CH:1]=[CH:2][CH:3]=3)=[C:25]3[N:26]=[C:22]([CH:23]=[CH:24]3)[C:21]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)=[C:20]3[NH:19][C:18]([CH:34]=[CH:33]3)=[C:17]([C:35]3[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=3)[C:16]3=[N:15][C:14]=2[CH:42]=[CH:41]3)[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=1.[Cu+2:54]

参加物

6

反応物 3

HCID 6344DichloromethaneHCID 701865,10,15,20-Tetraphenyl-21,22-dihydroporphyrinHCID 165397Cupric acetate monohydrate

生成物 1

HCID 135741320Copper, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N(21)-,N(22)-,N(23)-,N(24)-]-

試薬・触媒・溶媒 2

HCID 887Methanol溶媒HCID 6212Chloroform溶媒

実験手順

Tetraphenylporphyrin (II) (16.80 g., 27.3 mmol) is dissolved in 2000 ml of chloroform under reflux. Copper (II) acetate monohydrate (5.45 g., 27.3 mmol) is dissolved in 600 ml of methanol, and added dropwise to the methylene chloride solution in about 15 minutes. After the addition is over, the solution is refluxed for 30 minutes and cooled. The completion of the reaction is checked by UV-VIS spectrophotometry. The product IIa is isolated by evaporation of the solvents.

後処理

  1. temperatureunder reflux
  2. additionAfter the addition
  3. temperatureis refluxed for 30 minutes
  4. temperaturecooled
  5. customThe product IIa is isolated by evaporation of the solvents

出典と根拠

ORDレコード
ord-e56dc25a2c0b4674950da31342da095e
出典データセット
uspto-grants-1992_02
特許番号
US05091502

関連ノート

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