Dichloromethane → 4-chloro-2-(6-cyano-3,4-dihydro-2,2-dimethyl-2H-1-benzopyran-4-yl)pyridine N-oxide

反応式

[Cl:1][c:2]1[cH:3][c:4]([CH:8]2[CH2:9][C:10]([CH3:20])([CH3:21])[O:11][c:12]3[c:13]2[cH:14][c:15]([C:18]#[N:19])[cH:16][cH:17]3)[n:5][cH:6][cH:7]1.[Cl:22][c:23]1[cH:24][cH:25][cH:26][c:27]([C:28]([O:29][OH:31])=[O:30])[cH:32]1.[Cl:33][CH2:34][Cl:35]>>[Cl:1][c:2]1[cH:3][c:4]([CH:8]2[CH2:9][C:10]([CH3:20])([CH3:21])[O:11][c:12]3[c:13]2[cH:14][c:15]([C:18]#[N:19])[cH:16][cH:17]3)[n+:5]([O-:30])[cH:6][cH:7]1

参加物

反応物 3

HCID 6344Dichloromethane

HCID 70297m-Chloroperbenzoic acid

HCID 198956254-(4-chloro-2-pyridyl)-3,4-dihydro-2,2-dimethyl-2H-1-benzopyran-6-carbonitrile

生成物 1

HCID 536365624-chloro-2-(6-cyano-3,4-dihydro-2,2-dimethyl-2H-1-benzopyran-4-yl)pyridine N-oxide

出典と根拠

ORDレコード: ord-c2642e72c4c14cb99fe11838201a50dd
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…