Chlorotrimethylsilane → HCID 178423718、化合物
反応式
C[N-]C.C[N-]C.[CH3:7][C:8]1[CH:9]([C:16]2[CH:24]=[CH:23][CH:22]=[CH:21][C:17]=2[CH2:18][O:19][Ti+2:20])[C:10]([CH3:15])=[C:11]([CH3:14])[C:12]=1[CH3:13].C[Si](C)(C)[Cl:27]>CCCCC>[Cl-:27].[Cl-:27].[CH3:15][C:10]1[CH:9]([C:16]2[CH:24]=[CH:23][CH:22]=[CH:21][C:17]=2[CH2:18][O:19][Ti+2:20])[C:8]([CH3:7])=[C:12]([CH3:13])[C:11]=1[CH3:14]参加物
4
実験手順
To a solution of 2-(2,3,4,5-tetramethylcyclopentadienyl)benzyloxytitanium bis(dimethylamide) (0.84 g, 3.1 mmol) in pentane (15.2 mL) was added dropwise a solution of trimethylchlorosilane (3.67 g, 33.8 mmol) in pentane (5.0 mL) at 0° C. The mixture was stirred at room temperature for 15 hrs. 2-(2,3,4,5-Tetramethylcyclopentadienyl)benzyloxytitanium dichloride (1.00 g, yield 94.3%) was obtained as an yellow solid.