反応式
[Sb:1](=O)([O-])([O-])[O-].[Na+].[Na+].[Na+].[Sb].[CH2:10]([SH:20])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].Cl>O>[CH2:10]([SH:20])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[Sb+5:1]参加物
6
反応条件
- 温度
- 4 °C
実験手順
Sodium antimonate obtained from U.S. Antimony Corporation (9.49 g, 0.02347 mole) was placed in a reaction vessel and 1-decanethiol from Eastman Kodak (50 ml, 0.2347 mole) added and stirred. Concentrated hydrochloric acid (3.9 ml, 0.0468 mole) was added dropwise and an immediate temperature increase of 4° C. was observed. The mixture was heated and the byproduct of the reaction, water, was distilled over at 28° C. and a vacuum of 50 mm Hg. After 2.5 hours 45.57 g of antimony (V) decanethiol was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.
後処理
- temperatureThe mixture was heated
- distillationwas distilled over at 28° C.
出典と根拠
- ORDレコード
- ord-c01b6090979e444dbe4c074b43123026
- 出典データセット
- uspto-grants-1981_09
- 特許番号
- US04287118
関連ノート
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