関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | 1-Decanethiol | HCID 8917 | — |
| 反応物 | Antimonic acid, sodium salt | HCID 25469 | — |
| 反応物 | Antimony | HCID 5354495 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | antimony (V) decanethiol | HCID 86737980 | — |
反応手順
Sodium antimonate obtained from U.S. Antimony Corporation (9.49 g, 0.02347 mole) was placed in a reaction vessel and 1-decanethiol from Eastman Kodak (50 ml, 0.2347 mole) added and stirred. Concentrated hydrochloric acid (3.9 ml, 0.0468 mole) was added dropwise and an immediate temperature increase of 4° C. was observed. The mixture was heated and the byproduct of the reaction, water, was distilled over at 28° C. and a vacuum of 50 mm Hg. After 2.5 hours 45.57 g of antimony (V) decanethiol was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04287118 |
|---|
| 出典データセット | uspto-grants-1981_09 |
|---|
| ORD ID | ord-c01b6090979e444dbe4c074b43123026 |
|---|
| 出典メモ | uspto-grants-1981_09 |
|---|
