反应详情

温度

4 °C

Sodium antimonate obtained from U.S. Antimony Corporation (9.49 g, 0.02347 mole) was placed in a reaction vessel and 1-decanethiol from Eastman Kodak (50 ml, 0.2347 mole) added and stirred. Concentrated hydrochloric acid (3.9 ml, 0.0468 mole) was added dropwise and an immediate temperature increase of 4° C. was observed. The mixture was heated and the byproduct of the reaction, water, was distilled over at 28° C. and a vacuum of 50 mm Hg. After 2.5 hours 45.57 g of antimony (V) decanethiol was obtained. The product was filtered to remove unreacted sodium antimonate and the additional byproduct of the reaction, sodium chloride.

1. temperatureThe mixture was heated
2. distillationwas distilled over at 28° C.