Hydrochloric Acid → 1-Hydroxyanthraquinone

HRID 1578251ノート

反応式

HRID 1578251 の反応式
[N+]([C:4]1[C:17]2[C:16](=[O:18])[C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[C:9](=[O:19])[C:8]=2[CH:7]=[CH:6][CH:5]=1)([O-])=O.CN(C)C=[O:23].C([O-])=O.[Na+].Cl>O>[OH:23][C:4]1[C:17]2[C:16](=[O:18])[C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[C:9](=[O:19])[C:8]=2[CH:7]=[CH:6][CH:5]=1

参加物

6

反応物 4

HCID 313Hydrochloric AcidHCID 6228DimethylformamideHCID 67041-NitroanthraquinoneHCID 2723810Sodium Formate

生成物 1

HCID 85121-Hydroxyanthraquinone

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

1-Nitroanthraquinone (96.4%, 3.4%-dinitroanthraquinones), (7.6 g; 0.03 mole), dimethylformamide (50 ml), and sodium formate (4.1 g; 0.06 mole) were stirred at 130° C. for 17 hours. There was a slow evolution of gas during the reaction period. The reaction mass was cooled, mixed with water (300 ml) and acidified with 32% hydrochloric acid. The resulting suspension was stirred for one hour and filtered. The cake obtained was washed with water, then dried to give 1-hydroxyanthraquinone (6.6 g; 0.03 mole) which by gas chromatographic analysis contained 96.4% 1-hydroxyanthraquinone; 1.8% 1-nitroanthraquinone and 1.8% anthraquinone.

後処理

  1. customduring the reaction period
  2. temperatureThe reaction mass was cooled
  3. filtrationfiltered
  4. customThe cake obtained
  5. washwas washed with water
  6. customdried

出典と根拠

ORDレコード
ord-636476c8cd93408fa360e59f49fd6548
出典データセット
uspto-grants-1981_09
特許番号
US04292248

反応ノート

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