Cyclohexanol → 4-Cyclohexyloxy-7-nitro-2,5-bis(trifluoromethyl)benzimidazole

反応式

Cl[C:2]1[C:10]2[NH:9][C:8]([C:11]([F:14])([F:13])[F:12])=[N:7][C:6]=2[C:5]([N+:15]([O-:17])=[O:16])=[CH:4][C:3]=1[C:18]([F:21])([F:20])[F:19].[Na].[CH:23]1([OH:29])[CH2:28][CH2:27][CH2:26][CH2:25][CH2:24]1>>[CH:23]1([O:29][C:2]2[C:10]3[NH:9][C:8]([C:11]([F:14])([F:13])[F:12])=[N:7][C:6]=3[C:5]([N+:15]([O-:17])=[O:16])=[CH:4][C:3]=2[C:18]([F:21])([F:20])[F:19])[CH2:28][CH2:27][CH2:26][CH2:25][CH2:24]1

参加物

反応物 3

HCID 7966Cyclohexanol

HCID 5360545Sodium

HCID 1355549354-Chloro-7-nitro-2,5-bis(trifluoromethyl)benzimidazole

生成物 1

HCID 215585574-Cyclohexyloxy-7-nitro-2,5-bis(trifluoromethyl)benzimidazole

実験手順

4-Chloro-7-nitro-2,5-bis(trifluoromethyl)benzimidazole is reacted with the sodium sale of cyclohexanol to obtain 4-cyclohexyloxy-7-nitro-2,5-bis(trifluoromethyl)benzimidazole, m.w., 397.3.

出典と根拠

ORDレコード: ord-0a42712290834bb1b983242b10d36335
出典データセット: uspto-grants-1976_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US03939166

反応ノート

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