tert-Butyl mercaptan → 4-(Tert-butylthio)-7-nitro-2,5-bis-(trifluoromethyl)benzimidazole

HRID 1578737ノート

反応式

HRID 1578737 の反応式
Cl[C:2]1[C:10]2[NH:9][C:8]([C:11]([F:14])([F:13])[F:12])=[N:7][C:6]=2[C:5]([N+:15]([O-:17])=[O:16])=[CH:4][C:3]=1[C:18]([F:21])([F:20])[F:19].[K].[C:23]([SH:27])([CH3:26])([CH3:25])[CH3:24]>>[C:23]([S:27][C:2]1[C:10]2[NH:9][C:8]([C:11]([F:14])([F:13])[F:12])=[N:7][C:6]=2[C:5]([N+:15]([O-:17])=[O:16])=[CH:4][C:3]=1[C:18]([F:21])([F:20])[F:19])([CH3:26])([CH3:25])[CH3:24]

参加物

4

反応物 3

HCID 6387tert-Butyl mercaptanHCID 5462222PotassiumHCID 1355549354-Chloro-7-nitro-2,5-bis(trifluoromethyl)benzimidazole

生成物 1

HCID 215585754-(Tert-butylthio)-7-nitro-2,5-bis-(trifluoromethyl)benzimidazole

実験手順

4-Chloro-7-nitro-2,5-bis(trifluoromethyl)benzimidazole is reacted with the potassium derivative of tertbutanethiol to obtain 4-(tert-butylthio)-7-nitro-2,5-bis-(trifluoromethyl)benzimidazole, m.w., 387.3.

出典と根拠

ORDレコード
ord-7a053d79260e40ba8ca5d6887bbdb73b
出典データセット
uspto-grants-1976_02
特許番号
US03939166

反応ノート

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