Oxygen → Trioctyl phosphate

HRID 1578833

反応式

HRID 1578833 の反応式
[P:1]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])[O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[O:29]=O>CCCCC(C([O-])=O)CC.CCCCC(C([O-])=O)CC.[Co+2]>[P:1]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])=[O:29]

参加物

4

反応物 2

HCID 977OxygenHCID 76413Octyl phosphite

生成物 1

HCID 15733Trioctyl phosphate収率 91%

試薬・触媒・溶媒 1

HCID 8696Cobalt octoate触媒

実験手順

A mixture of 0.2 g. of cobalt octoate and 70 g. of trioctyl phosphite is warmed in vacuo (10 mm.) at 30°C while oxygen is added over a period of six hours. The mixture is stirred throughout this period by means of a magnetic stirrer. The product is washed with an aqueous alkaline solution to remove the cobalt catalyst, having a 91% yield of trioctyl phosphate.

後処理

  1. additionA mixture of 0.2 g
  2. additionis added over a period of six hours
  3. washThe product is washed with an aqueous alkaline solution
  4. customto remove the cobalt catalyst

出典と根拠

ORDレコード
ord-872a2dab69c84d7d96c8950da038a833
出典データセット
uspto-grants-1976_02
特許番号
US03939229

関連ノート

読み込み中…