Acetic Anhydride → HCID 12251437、化合物
反応式
[CH2:1]1[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:3][C:2]21[CH2:14][CH2:13][C:12](=NO)[CH2:11][CH2:10]2.C(OC(=O)C)(=[O:19])C>N1C=CC=CC=1>[CH2:1]1[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:3][C:2]21[CH2:14][CH2:13][C:12](=[O:19])[CH2:11][CH2:10]2参加物
4
実験手順
A solution of 3.1 g. spiro(cyclohexane-1,2'-indan)-4-one oxime [12] (prepared in Example 24B) and 6 ml. of acetic anhydride in 25 ml. of pyridine is allowed to stand at room temperature for about 6 hours. The reaction mixture is then poured into ice: water and the solid collected on a filter. The solid is recrystallized from Skellysolve B to give 2.94 g. (88% yield) of spiro(cyclohexane-1,2'-indan)-4-one, oxime acetate [13] having a melting point of 91° to 94° C.
後処理
- additionThe reaction mixture is then poured into ice
- customwater and the solid collected on a filter
- customThe solid is recrystallized from Skellysolve B
- customto give 2.94 g
出典と根拠
- ORDレコード
- ord-3e6294ef2e2f48e79034bd8b53942113
- 出典データセット
- uspto-grants-1976_01
- 特許番号
- US03932425
反応ノート
読み込み中…