Sodium Carbonate → 2-Ethylhexanoylmethylenetriphenylphosphorane

HRID 1581112ノート

反応式

HRID 1581112 の反応式
[Cl-].[O:2]=[C:3]([CH:24]([CH2:29][CH3:30])[CH2:25][CH2:26][CH2:27][CH3:28])[CH2:4][P+:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.C(=O)([O-])[O-].[Na+].[Na+]>O>[CH2:29]([CH:24]([CH2:25][CH2:26][CH2:27][CH3:28])[C:3]([CH:4]=[P:5]([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:2])[CH3:30]

参加物

4

反応物 2

HCID 10340Sodium CarbonateHCID 215614842-Oxo-3-ethylheptyltriphenylphosphonium chloride

生成物 1

HCID 215614912-Ethylhexanoylmethylenetriphenylphosphorane

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Crude 2-oxo-3-ethylheptyltriphenylphosphonium chloride (88 g.) was added to a solution of sodium carbonate (100 g.) in water (1 litre) and the mixture stirred vigorously for 24 hours. The mixture was then extracted with diethyl ether and the extracts dried over magnesium sulphate. The solvent was evaporated and the crude product (63.3 g.) recrystallised from petrol (b.p. 60°-80°C.) to give 2-ethylhexanoylmethylenetriphenylphosphorane, m.p. 105.5°-107.5°C. (Found: C, 80.2; H, 7.5. C27H31OP requires C, 80.5; H, 7.5%).

後処理

  1. extractionThe mixture was then extracted with diethyl ether
  2. dry with materialthe extracts dried over magnesium sulphate
  3. customThe solvent was evaporated
  4. customthe crude product (63.3 g.) recrystallised from petrol (b.p. 60°-80°C.)

出典と根拠

ORDレコード
ord-caecd330994142eb9376a3d1011e8b56
出典データセット
uspto-grants-1976_01
特許番号
US03935261

反応ノート

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