Carbon Dioxide → Carbon Dioxide

HRID 1581122ノート

反応式

HRID 1581122 の反応式
[O:1]=[P:2]12[O:13][P:11]3([O:14][P:4]([O:6][P:7]([O:10]3)([O:9]1)=[O:8])(=[O:5])[O:3]2)=[O:12].[Al+3].[Cl-:16].[Cl-:17].[Cl-].O=P(Cl)(Cl)Cl.P(Cl)(Cl)Cl.P(Cl)(Cl)(Cl)(Cl)Cl.O=POP=O.[C:39](=[O:41])=[O:40]>>[O:5]=[P:4]12[O:3][P:2]3([O:9][P:7]([O:10][P:11]([O:13]3)([O:14]1)=[O:12])(=[O:8])[O:6]2)=[O:1].[C:39](=[O:41])=[O:40].[Cl:16][Cl:17]

参加物

10

反応物 7

HCID 280Carbon DioxideHCID 14810Phosphorus trioxideHCID 14812Phosphorus oxide (P4O10)HCID 24387Phosphorus trichlorideHCID 24813Phosphorus oxychlorideHCID 24819Phosphorus pentachlorideHCID 6451240Aluminum(III) Chloride2 回

生成物 3

HCID 280Carbon DioxideHCID 14812Phosphorus oxide (P4O10)HCID 24526Chlorine

実験手順

A process of anhydrous carbo-chlorination of AlPO4 comprising the steps of introducing AlPO4 -containing material into a reactor zone; introducing chlorine and carbonaceous material into said reactor zone; heating the reactor zone to a temperature of from 600°-1200°C to form aluminum chlorides, phosphorous oxides, phosphorous chlorides, phosphorous oxychlorides and carbon oxides; separating the reaction products into three fractions by condensation, the first fraction being P2O5, the second fraction being AlCl3 and AlCl3 . POCl3, and the third fraction being PCl3, PCl5, P2O3, CO and CO2 ; and passing said fraction, which is gaseous, into an oxidizer to produce P2O5, CO2 and Cl2.

後処理

  1. customseparating the reaction products into three fractions
  2. customby condensation

出典と根拠

ORDレコード
ord-fa9bbbf90d4e46d5bcc9361ca3f99705
出典データセット
uspto-grants-1976_01
特許番号
US03935297

反応ノート

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