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p-Toluenesulfonic acid → HCID 70100107、化合物

HRID 1581907
ノート
印刷プレビュー

反応式

HRID 1581907 の反応式
[CH:1]([O:3][CH2:4][CH:5]([CH3:7])[CH3:6])=[CH2:2].[C:8]1([CH3:18])[CH:13]=[CH:12]C(S(O)(=O)=O)=[CH:10][CH:9]=1.C(N([CH2:24][CH3:25])CC)C.[C:26]([O:29][CH2:30][CH3:31])(=[O:28])C>C(OC(C)COCC)(=O)C>[CH2:4]([O:3][CH:1]([O:29][C:30]1[CH:31]=[CH:18][C:8]([CH:13]=[CH2:12])=[CH:9][CH:10]=1)[CH3:2])[CH:5]([CH3:7])[CH3:6].[OH:29][C:30]1[CH:31]=[CH:18][C:8]([CH:13]=[CH2:12])=[CH:9][CH:10]=1.[C:26]([O:29][C:8]([CH3:9])([CH3:13])[CH3:18])(=[O:28])[CH:24]=[CH2:25]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

6

反応物 4

HCID 6101p-Toluenesulfonic acidHCID 7992Vinyl isobutyl etherHCID 8471TriethylamineHCID 8857Ethyl Acetate

生成物 1

HCID 70100107HCID 70100107、化合物

試薬・触媒・溶媒 1

HCID 1713782-Propanol, 1-ethoxy-, 2-acetate溶媒2 回

反応条件

温度
60 °C

実験手順

The above polymer (A-48) (20 g) was dissolved in 80 g of propylene glycol monoethyl ether acetate (PGMEA) and the solution was heated at 60° C., and then the pressure was gradually reduced until 20 mmHg, thereby PGMEA and the moisture in the reaction system were azeotropically hydrated. After the azeotropic hydration, the temperature was lowered to 20° C., 2.2 g of isobutyl vinyl ether was added thereto, and further 3 mg of p-toluenesulfonic acid was added. After the addition, reaction was performed for 2 hours, and a small amount of triethylamine was added to neutralize the acid. Thereafter, ethyl acetate was added to the reaction solution, and the salt was removed by washing with ion exchange water. Further, ethyl acetate and water were distilled off under reduced pressure, thereby polymer A-16 was obtained.

後処理

  1. customwas lowered to 20° C.
  2. additionAfter the addition, reaction
  3. customthe salt was removed
  4. washby washing with ion exchange water
  5. distillationFurther, ethyl acetate and water were distilled off under reduced pressure
  6. customwas obtained

出典と根拠

ORDレコード
ord-ad5e0c7567b14f32bf459e74aca1bf7e
出典データセット
uspto-grants-2004_05
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US06733951B2

反応ノート

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