Benzyl Alcohol → HCID 178476834、化合物

HRID 1583732

反応式

HRID 1583732 の反応式
[OH:1][CH:2]([PH:4](=[O:6])[OH:5])[CH3:3].[CH2:7](O)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.O>C1C=CC=CC=1>[OH:1][CH:2]([PH:4](=[O:5])[O:6][CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[CH3:3]

参加物

5

反応物 3

HCID 244Benzyl AlcoholHCID 962WaterHCID 178476830HCID 178476830、化合物

生成物 1

HCID 178476834HCID 178476834、化合物収率 91.2%

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

A solution of α-hydroxyethylphosphinic acid (5.5 g) and benzyl alcohol (2.26 g) in benzene (50 ml) was heated for 8 hours with removal of water through a Dean-Stark apparatus. After cooling, the reaction mixture was washed with water, dried over magnesium sulfate and concentrated in vacuo to give 3.65 g (91.2%) of benzyl α-hydroxyethylphosphinate (Compound No. 36).

後処理

  1. temperatureAfter cooling
  2. washthe reaction mixture was washed with water
  3. dry with materialdried over magnesium sulfate
  4. concentrationconcentrated in vacuo

出典と根拠

ORDレコード
ord-16302dc960c74e4580f5028245e59782
出典データセット
uspto-grants-1985_11
特許番号
US04554111

関連ノート

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