Azobisisobutyronitrile → (CH3O)3Si(CH2)3SCH2CH2CH2NHCONH2

HRID 1583814

反応式

HRID 1583814 の反応式
[SH:1][CH2:2][CH2:3][CH2:4][Si:5]([O:10][CH3:11])([O:8][CH3:9])[O:6][CH3:7].[CH2:12]([NH:15][C:16]([NH2:18])=[O:17])[CH:13]=[CH2:14].CC(N=NC(C#N)(C)C)(C#N)C>>[Si:5]([CH2:4][CH2:3][CH2:2][S:1][CH2:14][CH2:13][CH2:12][NH:15][C:16]([NH2:18])=[O:17])([O:10][CH3:11])([O:6][CH3:7])[O:8][CH3:9]

参加物

4

反応物 3

HCID 6547AzobisisobutyronitrileHCID 11181AllylureaHCID 20473(3-Mercaptopropyl)trimethoxysilane

生成物 1

HCID 131713687(CH3O)3Si(CH2)3SCH2CH2CH2NHCONH2

反応条件

温度
90 °C

実験手順

70 grams of mercaptopropyltrimethoxy silane and 35.5 gms. of allylurea were weighed into a flask equipped as in Example 1. The contents of the flask were heated to about 90° C. and 0.3 gm. of Vazo 64 was used. The temperature indicated an exotherm to about 145° C. which was controlled back down to about 100° C. for a total of 6® hours and it was then cooled. Titration of a sample showed about 71% reaction of the mercaptan. The material was filtered. The proton NMR analysis showed a structure consistent with the title compound. There was unreacted allylurea present at less than 25%.

後処理

  1. customequipped as in Example 1
  2. customexotherm to about 145° C.
  3. customwas controlled back down to about 100° C. for a total of 6® hours and it
  4. temperaturewas then cooled
  5. filtrationThe material was filtered

出典と根拠

ORDレコード
ord-c38c15bb34464d9699e196c5198c112f
出典データセット
uspto-grants-1985_11
特許番号
US04554354

関連ノート

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