Naphthalene → Lithium Naphthalene

HRID 1586625ノート

反応式

HRID 1586625 の反応式
[Li:1].[CH:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1>>[Li:1].[CH:10]1[C:11]2[C:6](=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:7]=[CH:8][CH:9]=1

参加物

3

反応物 2

HCID 931NaphthaleneHCID 3028194Lithium

生成物 1

HCID 57466756Lithium Naphthalene

実験手順

Lithium shot (1.7 grams) packed in mineral oil (Lithcoa Corporation) was magnetically stirred with naphthalene (15 grams) in dry freshly distilled tetrahydrofuran (50 milliliters) for 16 hours at 25° C. in an argon purged amber sure-seal bottle equipped with a rubber septum. The resultant dark green lithium naphthalide solution was 2 molar in concentration as determined by titration with 0.1 molar hydrochloric acid and by size exclusion chromatographic analysis of the polymeric products obtained after reaction with multiblock component monomers.

後処理

  1. dry with materialin dry freshly distilled tetrahydrofuran (50 milliliters) for 16 hours at 25° C. in an argon
  2. custompurged
  3. customamber sure-seal bottle
  4. customequipped with a rubber septum
  5. concentrationin concentration
  6. customobtained
  7. customafter reaction with multiblock component monomers

出典と根拠

ORDレコード
ord-102b6d789f974737b7d17fe7c19a4db1
出典データセット
uspto-grants-1993_06
特許番号
US05215846

反応ノート

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