1-(Methylsulphonylaminocarbonyl)-3-nitrobenzene → 1-(Methylsulphonylaminocarbonyl)-3-aminobenzene
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([C:10]([NH:12][S:13]([CH3:16])(=[O:15])=[O:14])=[O:11])[CH:7]=[CH:8][CH:9]=1)([O-])=O>C(O)C.[Pd]>[NH2:1][C:4]1[CH:5]=[C:6]([C:10]([NH:12][S:13]([CH3:16])(=[O:15])=[O:14])=[O:11])[CH:7]=[CH:8][CH:9]=1参加物
4
実験手順
3-Nitro-N-(methanesulfonyl)phenylcarboxamide (1.6 g) was dissolved in 50 ml of ethanol, treated with 510 mg of 10% palladium/carbon catalyst, and hydrogenated on a Parr apparatus at 30 psi for 15 minutes. The reaction mixture was filtered through Celite and concentrated to give the title compound (1.1 g) as a white solid.
後処理
- filtrationThe reaction mixture was filtered through Celite
- concentrationconcentrated
出典と根拠
- ORDレコード
- ord-82c4bf63241142d49f5adee5b6a3311a
- 出典データセット
- uspto-grants-1993_06
- 特許番号
- US05220018
反応ノート
読み込み中…