1,2,3,4-Butanetetracarboxylic acid → 1,2,3,4-Butanetetracarboxylic Acid Sodium Dihydrogen Phosphate

HRID 1588173ノート

反応式

HRID 1588173 の反応式
[CH2:1]([C:14]([OH:16])=[O:15])[CH:2]([C:11]([OH:13])=[O:12])[CH:3]([C:8]([OH:10])=[O:9])[CH2:4][C:5]([OH:7])=[O:6].[P:17]([O-:21])([OH:20])([OH:19])=[O:18].[Na+:22]>>[CH2:4]([C:5]([OH:7])=[O:6])[CH:3]([C:8]([OH:10])=[O:9])[CH:2]([C:11]([OH:13])=[O:12])[CH2:1][C:14]([OH:16])=[O:15].[P:17]([O-:21])([OH:20])([OH:19])=[O:18].[Na+:22]

参加物

3

反応物 2

HCID 155601,2,3,4-Butanetetracarboxylic acidHCID 23672064Monosodium phosphate

生成物 1

HCID 867429131,2,3,4-Butanetetracarboxylic Acid Sodium Dihydrogen Phosphate収率 90%

実験手順

An aqueous treating bath was prepared containing a given concentration of 1,2,3,4-butanetetracarboxylic acid and sodium dihydrogen phosphate in an agent to catalyst gfw ratio of 1:1.15. An all-cotton desized, scoured and bleached 80×80 printcloth weighing 3.2 oz/yd2 was thoroughly wetted by immersion in this treating bath, was passed between the rolls of a wringer, was again immersed in the treating bath, and was again passed through the wringer, the pressure of the wringer rolls being sufficient to give a wet pickup of 90-100% of aqueous mixture on the fabric, based on the original weight of fabric sample. The fabric was then dried in a forced draft oven at 85° C. for 5 minutes, and was heat-cured in a second forced draft oven at 180° C. for 90 seconds. The fabric was subsequently machine laundered and tumble dried. A sample finished with 5% DMDHEU and a 1.8% magnesium chloride hexahydrate-citric acid catalyst in a 20:1 gfw ratio was included as a control. The textile properties after one laundering cycle are given in Table XI

後処理

  1. customAn aqueous treating bath was prepared
  2. customwas thoroughly wetted by immersion in this treating bath

出典と根拠

ORDレコード
ord-238fb6283ea64ae4a7aa1e7ea4bb3eef
出典データセット
uspto-grants-1993_06
特許番号
US05221285

反応ノート

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