Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetate → HCID 54328202、化合物

HRID 1596182ノート

反応式

HRID 1596182 の反応式
[CH2:1]([O:3][C:4](=[O:23])[CH:5]=[C:6]1[CH2:9][N:8](C(C2C=CC=CC=2)C2C=CC=CC=2)[CH2:7]1)[CH3:2].[H][H]>C(O)C.[OH-].[OH-].[Pd+2]>[CH2:1]([O:3][C:4](=[O:23])[CH2:5][CH:6]1[CH2:9][NH:8][CH2:7]1)[CH3:2]

参加物

5

反応物 2

HCID 53428664Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetateHCID 178418361HCID 178418361、化合物

生成物 1

HCID 54328202HCID 54328202、化合物

試薬・触媒・溶媒 2

HCID 9942167Palladium hydroxide触媒HCID 702Ethanol溶媒

実験手順

To a solution of (1-benzhydrylazetidin-3-ylidene)-acetic acid ethyl ester (5.0 g, 16 mmol) in ethanol (200 mL) was added palladium hydroxide on carbon (1.5 g). This mixture was vigorously shaken under a 50 psi hydrogen atmosphere for 24 hrs, then filtered and concentrated to give an oil, used without additional purification.

後処理

  1. filtrationfiltered
  2. concentrationconcentrated
  3. customto give an oil
  4. customused without additional purification

出典と根拠

ORDレコード
ord-0d8c71ddcce741c880b4bf11130e10cc
出典データセット
uspto-grants-2001_09
特許番号
US06291457B1

反応ノート

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