Palladium hydroxide (HCID 9942167)

名称と識別子

優先名称: Palladium hydroxide
IUPAC: palladium(2+) dihydroxide
現地名: 水酸化パラジウム / 炭素
英語名: Palladium hydroxide
分子式: H2O2Pd
分子量: 140.43

名称と別名

Palladium hydroxide12135-22-7Palladium(II) hydroxidePalladium hydroxide on carbonPearlman's catalystPalladium dihydroxidePalladium hydroxide (Pd(OH)2)HRE96R2PEXPEARLMAN'S CATALYST [MI]RefChem:169625EINECS 235-219-2UNII-HRE96R2PEX

名称をさらに表示

水酸化パラジウム / 炭素 (Pd20%) (約50%水湿潤品)パラジウム(II)ジヒドロキシド水酸化パラジウム(II)水酸化パラジウム/炭素粉末水酸化パラジウム水酸化パラジウム / 炭素 (Pd 20%) (約50%水湿潤品)水酸化パラジウム (パラジウム, 酸化パラジウム(II) 含む) / 炭素 (約50%水湿潤品)Pearlman触媒 (パラジウム, 酸化パラジウム(II) 含む) (約50%水湿潤品)水酸化パラジウム ON CARBON 5%水酸化パラジウム ON CARBON, 20 WT.% 50% WATER水酸化パラジウム-活性炭素 (PD 20%)(約50%含水)パラジウム-活性炭パラジウム-炭素水酸化パラジウム, 炭素担持水酸化パラジウム, Pd 20% on carbon, nominally 50% water, パールマンの触媒水酸化パラジウム / 炭素PD(OH)2Pd(OH)2/C[Pd(cinnamyl)Cl]2PALLADIUM ON CARBONPALLADIUM CARBONPALLADIUM ON ACTIVATED CARBONPd(OH)PALLADIUM ON CHARCOAL

Palladium hydroxide on carbon(20%)Palladium hydroxide on carbon(10%)Palladium Hydroxide 20% on Carbon, ca.50% WaterPearlmans CatalystdihydroxypalladiumpalladiumhydroxidePearlman catalystPALLADIUM(2+) DIHYDROXIDE

データベース識別子

CAS: 12135-22-7
PubChem CID: 9942167
UNII: HRE96R2PEX
EC Number: 235-219-2
Nikkaji: J154.801H

物性

構造計算による物性

極性表面積: 2 Å²
水素結合供与体数: 2
水素結合受容体数: 2
回転可能結合数: 0
重原子数: 3
形式電荷: 0
複雑度: 0

実験および物理化学的性質

Physical DescriptionBlack odorless powder; [Alfa Aesar MSDS]

物理化学的性質

比重(密度): 3.44 · 3.44[at 20℃]
貯蔵温度: Inert atmosphere,Room Temperature
外見: 粉
色: 白い
水溶解度: 不溶性
Merck: 14 · 14,7060
InChI: InChI=1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
InChIKey: NXJCBFBQEVOTOW-UHFFFAOYSA-L
SMILES: [Pd](O)O
CAS データベース: 12135 · 12135-22-7(CAS DataBase Reference)
EPAの化学物質情報: 2 · Palladium hydroxide (Pd(OH)2) (12135-22-7)

化学的性質

化学的特性Palladium hydroxide is black powder

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 0.6% (1 of 167) of reports.

Danger

H272 (77.8%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]；H302 (63.5%): Harmful if swallowed [Warning Acute toxicity, oral]；H317 (63.5%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H318 (63.5%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H319 (16.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H413 (19.2%): May cause long lasting harmful effects to aquatic life [Hazardous to the aquatic environment, long-term hazard]

P210, P220, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P330, P333+P317, P337+P317, P362+P364, P370+P378, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 167 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 1 of 167 reports by companies.；There are 6 notifications provided by 166 of 167 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 2 件

Status: Active Update: 28-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/19423

Palladium hydroxide (Pd(OH)2): Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryMay cause irritation; [Alfa Aesar MSDS] See Palladium oxide and Palladium chloride.

Hazard Classes and CategoriesOx. Sol. 3 (77.8%)；Acute Tox. 4 (63.5%)；Skin Sens. 1 (63.5%)；Eye Dam. 1 (63.5%)；Eye Irrit. 2 (16.8%)；Aquatic Chronic 4 (19.2%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

2.0 [mg/m3]

22 [mg/m3]

130 [mg/m3]

法規制情報

Regulatory Information · 2 件

Status: Active Update: 28-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/19423

Palladium hydroxide (Pd(OH)2): Does not have an individual approval but may be used under an appropriate group standard

安全データ

wgk: 3
tsca: TSCA listed
ridadr: UN1325
hs_code: 38151200
risk_code: 11-36/37/38
化審法: (1)-1141
hazard_code: F,Xi
safety_code: 22-24/25-14-36-26-20/21-36/37/39-33-27-16-7/9
hazard_class: 4.1
packing_group: III
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

UsesCommercial Pearlman's catalyst is composed of 20% palladium hydroxide (Pd(OH)2) on carbon; Used as a catalyst for hydrogenolysis of benzyl-nitrogen and benzyl-oxygen bonds; [Merck Index]

General Manufacturing InformationPalladium hydroxide (Pd(OH)2): ACTIVE

応用分野

使用Palladium hydroxide is usually used as a catalyst for arylation reactions.

一般的な説明This product has been enhanced for energy efficiency.

上流・下流製品情報

下流製品

テトラヒドロジフェルロイルメタン 3-(2-クロロエチル)-6,7,8,9-テトラヒドロ-2-メチル-4H-ピリド[1,2-a]ピリミジン-4-オン Methyl 3-((piperidin-4-yl)methyl)benzoate Diethyl pyrimidine-4,6-dicarboxylate 8-アミノイソキノリンイソチオシアン酸1,3-ベンゾジオキソール-5-イル 4-(3-アミノプロピル)-2,4-ジヒドロ-3H-ピラゾール-3-オン 4-((1-(tert-Butoxycarbonyl)piperidin-4-yl)methyl)benzoic acid 3,4-ジヒドロキシベンゼンプロピオン酸 Methyl 4-((piperidin-4-yl)methyl)benzoate 3,7-ジヒドロ-1-メチル-1H-プリン-2,6-ジオン 1-(2,4-Dichloro-5-fluoro-3-methoxyphenyl)ethanone

サプライヤー50 社

北京华美互利生物化工010-56205725 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

上海腾准生物科技有限公司19821570922 · [email protected]

T&W GROUP021-61551611 13296011611 · [email protected]

水酸化パラジウム / 炭素

基本情報