4-Vinylpyridine → HCID 22975755、化合物
反応式
[CH2:1]1[C:6]2([CH2:11][CH2:10][CH:9]([CH2:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])[CH2:8][CH2:7]2)[CH2:5][CH2:4][NH:3][CH2:2]1.[CH:18]([C:20]1[CH:25]=[CH:24][N:23]=[CH:22][CH:21]=1)=[CH2:19]>C(#N)C>[N:23]1[CH:24]=[CH:25][C:20]([CH2:18][CH2:19][N:3]2[CH2:2][CH2:1][C:6]3([CH2:11][CH2:10][CH:9]([CH2:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])[CH2:8][CH2:7]3)[CH2:5][CH2:4]2)=[CH:21][CH:22]=1参加物
4
実験手順
A solution of 0.48 g (2.0 mmol) of the intermediate from Example 1, Step C and 0.21 g (2.0 mmol) 4-vinylpyridine in 6 ml acetonitrile were heated at 80° C. over night. The solvent was removed under reduced pressure, and the remaining solid title compound was purified by stirring several times with tert.-butylmethylether, filtered with suction, and dried in vacuo.
後処理
- customThe solvent was removed under reduced pressure