Sulfuric Acid → 2,3,6,7,10,11-Hexamethoxytriphenylene
反応式
S(=O)(=O)(O)O.[CH3:6][O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[O:14][CH3:15]>[Fe](Cl)(Cl)Cl>[CH3:6][O:7][C:8]1[C:9]([O:14][CH3:15])=[CH:10][C:11]2[C:12]3[C:11](=[CH:10][C:9]([O:14][CH3:15])=[C:8]([O:7][CH3:6])[CH:13]=3)[C:12]3[C:11](=[CH:10][C:9]([O:14][CH3:15])=[C:8]([O:7][CH3:6])[CH:13]=3)[C:12]=2[CH:13]=1参加物
4
実験手順
In a 2-liter three-necked flask cooled with ice, 135 ml of ice water was placed, and 490 ml of concentrated sulfuric acid was gradually added to the ice water with stirring to prepare a sulfuric acid solution. Subsequently, 150 g of iron(III) chloride was added to the sulfuric acid solution at room temperature, and after reaction of 1 hour, 30 g of 1,2-dimethoxybenzene was further added to prepare a reaction mixture. After reaction of 3 hours, the reaction mixture was cooled with ice, and 1 liter of ice water was gradually added to the reaction mixture. After stirring of 1 hour, the reaction mixture was filtered through a glass filter to obtain crude crystals of the above compound (a) of 13 g (yield: 43%).