Peracetic Acid → 4-Tert-octylcatechol

HRID 1605628

反応式

HRID 1605628 の反応式
[C:1]([C:9]1[CH:14]=[CH:13][C:12]([OH:15])=[CH:11][CH:10]=1)([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:3])[CH3:2].CCC(OO)=[O:19].C(OO)(=O)C>CC(C)=O>[C:1]([C:9]1[CH:14]=[C:13]([OH:19])[C:12](=[CH:11][CH:10]=1)[OH:15])([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:2])[CH3:3]

参加物

5

反応物 3

HCID 6585Peracetic AcidHCID 88144-Tert-octylphenol2 回HCID 65136Perpropionic acid

生成物 1

HCID 708284-Tert-octylcatechol収率 61%

試薬・触媒・溶媒 1

HCID 180Acetone溶媒2 回

実験手順

The procedure of Example 8 was followed, except 20 ml of acetone was added as a solvent for para-tert.-octyl phenol and 4.5g (0.05 mol) of perpropionic acid in the form of about 25 weight% acetone solution was added over 20 minutes in place of peracetic acid. Consequently, the conversion of para-tert.-octyl phenol was 6.8%, 4-tert.-octyl pyrocatechol was formed in a yield of 61% based on the converted octyl phenol and the conversion of perpropionic acid was 100%.

出典と根拠

ORDレコード
ord-021a4408e9c9420987461663e7b55917
出典データセット
uspto-grants-1976_04
特許番号
US03950437

関連ノート

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