Sodium Azide → 4-Azidocarbonylphthalic anhydride

HRID 1605814

反応式

HRID 1605814 の反応式
[N-:1]=[N+:2]=[N-:3].[Na+].Cl[C:6]([C:8]1[CH:9]=[C:10]2[C:15](=[O:16])[O:14][C:12](=[O:13])[C:11]2=[CH:17][CH:18]=1)=[O:7]>CC(C)=O>[N:1]([C:6]([C:8]1[CH:9]=[C:10]2[C:15](=[O:16])[O:14][C:12](=[O:13])[C:11]2=[CH:17][CH:18]=1)=[O:7])=[N+:2]=[N-:3]

参加物

4

反応物 2

HCID 33557Sodium AzideHCID 70998Trimellitic anhydride chloride

生成物 1

HCID 538062294-Azidocarbonylphthalic anhydride

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

A total of 3.25 g of sodium azide was added in portions to a solution of 10.5 g of 4-chlorocarbonylphthalic anhydride in 100 ml of acetone. The mixture was allowed to stand for 17 hours at room temperature (circa 25°C) after which the yellow solution so obtained was evaporated to dryness under reduced pressure. There was thus obtained a substantially quantitative yield of 4-azidocarbonylphthalic anhydride in the form of a crystalline solid having a melting point of 100° to 103°C with decomposition.

後処理

  1. custom(circa 25°C) after which the yellow solution so obtained
  2. customwas evaporated to dryness under reduced pressure

出典と根拠

ORDレコード
ord-bba363dadea54fd6a64cca994e568a00
出典データセット
uspto-grants-1976_04
特許番号
US03951922

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