Sodium Hydroxide → HCID 21542730、化合物

HRID 1606393ノート

反応式

HRID 1606393 の反応式
[C:1](Cl)(=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9](Cl)=[O:10].Cl[C:15](Cl)=[C:16](Cl)Cl.[CH3:20][NH:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27].[OH-].[Na+]>O>[CH3:20][N:21]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:15][CH3:16])[C:1](=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9]([N:21]([CH3:20])[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])=[O:10]

参加物

6

反応物 4

HCID 14798Sodium HydroxideHCID 31373TetrachloroethyleneHCID 37079N-MethylhexylamineHCID 67165Azelaoyl chloride

生成物 1

HCID 21542730HCID 21542730、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

10.5 grams of azeloylchloride were placed in a container holding 140 milliliters of tetrachloroethylene and dissolved. To the resulting mixture were added 9.2 grams of N-methyl-N-hexylamine, and 1.6 grams of NaOH dissolved in 200 milliliters of water. The completed mixture was agitated for 10-15 minutes; afterwards the organic layer was separated, washed with a dilute aqueous HCl solution. Following this the organic layer was washed with a 10% aqueous Na2CO3 solution and then washed with water. The washed organic layer was dried by contacting with MgSO4 and then the tetrachloroethylene was removed by application of a vacuum.

後処理

  1. dissolutiondissolved
  2. customafterwards the organic layer was separated
  3. washwashed with a dilute aqueous HCl solution
  4. washwas washed with a 10% aqueous Na2CO3 solution
  5. washwashed with water
  6. customThe washed organic layer was dried
  7. customthe tetrachloroethylene was removed by application of a vacuum

出典と根拠

ORDレコード
ord-7ad7f1cd93754f1798ca634c3bde4ba4
出典データセット
uspto-grants-1976_04
特許番号
US03953346

反応ノート

読み込み中…