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Water → Sodium stearyl succinate

HRID 1606791
ノート
印刷プレビュー

反応式

HRID 1606791 の反応式
[CH2:1]([CH:19]([CH2:23][C:24]([OH:26])=O)C(O)=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]CCC.[OH-:27].[Na+:28].[OH2:29]>CC(C)=O>[C:24]([O:26][CH2:24][CH2:23][CH2:19][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])(=[O:26])[CH2:23][CH2:19][C:1]([O-:29])=[O:27].[Na+:28]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

5

反応物 3

HCID 962WaterHCID 14798Sodium HydroxideHCID 110691Octadecylsuccinic acid

生成物 1

HCID 23673896Sodium stearyl succinate収率 98.5%

試薬・触媒・溶媒 1

HCID 180Acetone溶媒2 回

反応条件

温度
40 °C

実験手順

In a 2000 ml. Erlenmeyer flask, there were placed 150 g. of monostearyl succinic acid (acid value, 156.7) and 1200 ml. of acetone. This mixture was first warmed and stirred to effect solution and then cooled to 40°C., at which point 17.3 g. of sodium hydroxide in 100 ml. of water were slowly added. The addition step was accomplished with vigorous agitation of the mixture, while the temperature of the acetone solution was always maintained at 40°-43°C. throughout said step. The resulting reaction mixture was then stirred for a further 15 minutes, cooled down to 10°-15°C. and filtered with suction. The filter cake so obtained was washed twice with separate 100 ml. portions of cold acetone and sucked dry on the filter funnel. After drying the product in a vacuum oven at 50°C., it was found that a yield of 157.5 g. (98.5%) of sodium stearyl succinate was obtained. This particular salt, which was obtained in the form of a white powder, gave a 0.1% (W/V) aqueous dispersion at 25°C. and a 1% dispersion at 50°C.

後処理

  1. temperatureThis mixture was first warmed
  2. additionThe addition step
  3. temperaturewas always maintained at 40°-43°C.
  4. customThe resulting reaction mixture
  5. stirringwas then stirred for a further 15 minutes
  6. temperaturecooled down to 10°-15°C.
  7. filtrationfiltered with suction
  8. customThe filter cake so obtained
  9. washwas washed twice
  10. customwith separate 100 ml
  11. dry with materialportions of cold acetone and sucked dry on the filter funnel
  12. customAfter drying the product in a vacuum oven at 50°C.

出典と根拠

ORDレコード
ord-91b90ee236a54dec9a85c957e84bc2ef
出典データセット
uspto-grants-1976_04
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US03953616

反応ノート

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このページの内容参加物反応条件実験手順後処理出典と根拠反応ノート