Hydrogen Bromide → Dibutylammonium bromide

HRID 1607202ノート

反応式

HRID 1607202 の反応式
[CH3:1][CH2:2][CH2:3][CH2:4][NH:5][CH2:6][CH2:7][CH2:8][CH3:9].[Br-:10].[CH2:11]([NH2+:15][CH2:16][CH2:17][CH2:18][CH3:19])[CH2:12][CH2:13][CH3:14].Br.CCOCC>C(O)C>[CH2:4]([NH2+:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:3][CH2:2][CH3:1].[Br-:10].[CH2:11]([NH2+:15][CH2:16][CH2:17][CH2:18][CH3:19])[CH2:12][CH2:13][CH3:14]

参加物

7

反応物 4

HCID 260Hydrogen BromideHCID 3283Diethyl EtherHCID 8148Dibutylamine2 回HCID 3014639Dibutylammonium bromide

生成物 2

HCID 3014639Dibutylammonium bromide収率 83.7%HCID 4094028HCID 4094028、化合物

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒2 回

実験手順

A series of di-n-butyl ammonium salts were prepared utilizing an absolute ethanol solution of di-N-butylamine. In preparing di-n-butylammonium bromide, hydrogen bromide gas was introduced into a solution of 585 grams of di-n-butylamine in absolute ethanol until the solution was saturated. The reaction vessel was in an ice bath during the addition. The solution was then treated with ether followed by further cooling to induce crystallization. The product was isolated by filtration, washed thoroughly with ether, and dried for about 12 hours in a vacuum oven (80° C. at about 15 torr). There was obtained an 83.7% yield of di-n-butylammonium bromide, MP 295°-296.5° C.

後処理

  1. additionThe reaction vessel was in an ice bath during the addition
  2. temperatureby further cooling
  3. customcrystallization
  4. customThe product was isolated by filtration
  5. washwashed thoroughly with ether
  6. customdried for about 12 hours in a vacuum oven (80° C. at about 15 torr)

出典と根拠

ORDレコード
ord-94ccafa9279747bd8d2713525ab79362
出典データセット
uspto-grants-1989_09
特許番号
US04863984

反応ノート

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