Terephthaloyl chloride → N,N'-Bis-(4-phenoxyphenyl)-2,3,5,6-tetrafluoroterephthalamide

HRID 1608091ノート

反応式

HRID 1608091 の反応式
[O:1]([C:8]1[CH:14]=[CH:13][C:11]([NH2:12])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[F:15][C:16]1[C:24]([F:25])=[C:23]([C:26](Cl)=[O:27])[C:22]([F:29])=[C:21]([F:30])[C:17]=1[C:18](Cl)=[O:19].C(Cl)(=O)[C:32]1[CH:40]=[CH:39][C:35](C(Cl)=O)=[CH:34][CH:33]=1.[Cl-].[Al+3].[Cl-].[Cl-]>ClCCCl.CN(C=O)C>[O:1]([C:8]1[CH:9]=[CH:10][C:11]([NH:12][C:18](=[O:19])[C:17]2[C:16]([F:15])=[C:24]([F:25])[C:23]([C:26]([NH:12][C:11]3[CH:13]=[CH:14][C:8]([O:1][C:32]4[CH:33]=[CH:34][CH:35]=[CH:39][CH:40]=4)=[CH:9][CH:10]=3)=[O:27])=[C:22]([F:29])[C:21]=2[F:30])=[CH:13][CH:14]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

7

反応物 4

HCID 7488Terephthaloyl chlorideHCID 8764(4-Aminophenoxy)benzeneHCID 6451240Aluminum(III) ChlorideHCID 132553402,3,5,6-Tetrafluorobenzene-1,4-dicarbonyl dichloride

生成物 1

HCID 19920040N,N'-Bis-(4-phenoxyphenyl)-2,3,5,6-tetrafluoroterephthalamide

試薬・触媒・溶媒 2

HCID 111,2-Dichloroethane溶媒HCID 6228Dimethylformamide溶媒

実験手順

N,N'-Bis-(4-phenoxyphenyl)-2,3,5,6-tetrafluoroterephthalamide was prepared from p-phenoxyaniline and 2,3,5,6-tetrafluoroterephthaloyl chloride. This amide (6.0108 g, 0.0105 moles) was polymerized with terephthaloyl chloride(2.1316 g, 0.0105 moles) by the procedure of Example 27. The amounts of aluminum chloride, DMF and DCE used were 12.55 g (0.094 moles), 3.3 mL (0.042 moles) and 60 mL, respectively. The white fibrous polymer which wasobtained had the repeat unit ##STR45##

出典と根拠

ORDレコード
ord-1e858617249a41de8cb0af53e6ebb9a2
出典データセット
uspto-grants-1989_09
特許番号
US04868271

反応ノート

読み込み中…