3,3-Dinitroazetidine → 3,3-Dinitroazetidinium 2,4-dinitroimidazolate

HRID 1608676ノート

反応式

HRID 1608676 の反応式
[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH:6][CH2:5]1)([O-:3])=[O:2].[N+:11]([C:14]1[NH:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12]>C(#N)C>[N+:11]([C:14]1[N-:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12].[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH2+:6][CH2:5]1)([O-:3])=[O:2]

参加物

4

反応物 2

HCID 52317063,3-DinitroazetidineHCID 178526857HCID 178526857、化合物

生成物 1

HCID 1317189183,3-Dinitroazetidinium 2,4-dinitroimidazolate収率 95%

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

3,3-Dinitroazetidine free base (1.0 g) was added to a solution of 2,4-dinitroimidazole (1.07 g) in 50 ml of warm acetonitrile. The solution was allowed to cool and the majority of the solvent evaporated. The remaining slurry was filtered and dried to give 1.98 g of the resultant product, 3,3-dinitroazetidinium 2,4-dinitroimidazolate (95% yield).

後処理

  1. temperatureto cool
  2. customthe majority of the solvent evaporated
  3. filtrationThe remaining slurry was filtered
  4. customdried

出典と根拠

ORDレコード
ord-f2cc1d08b8f14befacdfcb47b96c50ce
出典データセット
uspto-grants-1995_03
特許番号
US05395945

反応ノート

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