Ethyl benzoylacetate → 1-benzoyl-6-bromo-2,7-dihydro-3-methyl-2,7-dioxo-3H-dibenzo[f,ij]isoquinoline

反応式

C(O[C:4](=[O:14])[CH2:5][C:6](=[O:13])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)C.[CH3:15][NH:16][C:17]1[C:30]2[C:29](=O)[C:28]3[C:23](=[CH:24][CH:25]=[CH:26][CH:27]=3)[C:22](=[O:32])[C:21]=2[C:20]([Br:33])=[CH:19][CH:18]=1>>[C:6]([C:5]1[C:4](=[O:14])[N:16]([CH3:15])[C:17]2[CH:18]=[CH:19][C:20]([Br:33])=[C:21]3[C:22](=[O:32])[C:23]4[CH:24]=[CH:25][CH:26]=[CH:27][C:28]=4[C:29]=1[C:30]=23)(=[O:13])[C:7]1[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=1

参加物

反応物 2

HCID 7170Ethyl benzoylacetate

HCID 314189,10-Anthracenedione, 1-bromo-4-(methylamino)-

生成物 1

HCID 118585271-benzoyl-6-bromo-2,7-dihydro-3-methyl-2,7-dioxo-3H-dibenzo[f,ij]isoquinoline

実験手順

Benzoylacetic acid ethyl ester is reacted with 1-methylamino-4-bromoanthraquinone in a solvent to obtain 1-benzoyl-6-bromo-2,7-dihydro-3-methyl-2,7-dioxo-3H-dibenzo[f,ij]isoquinoline.

出典と根拠

ORDレコード: ord-360aa47db9e54e64a7bef26783001856
出典データセット: uspto-grants-2006_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06984032B2

反応ノート

読み込み中…