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4-Methoxyphenol → 8-(Trichlorosilyl)octyl 2-methylprop-2-enoate

HRID 1613475
ノート
印刷プレビュー

反応式

HRID 1613475 の反応式
[C:1]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:13]=[CH2:14])(=[O:5])[C:2]([CH3:4])=[CH2:3].COC1C=CC(O)=CC=1.[Cl:24][SiH:25]([Cl:27])[Cl:26]>O1CCCC1.O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4]>[C:1]([O:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][Si:25]([Cl:27])([Cl:26])[Cl:24])(=[O:5])[C:2]([CH3:4])=[CH2:3]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

6

反応物 3

HCID 90154-MethoxyphenolHCID 24811TrichlorosilaneHCID 144013997-Octenyl methacrylate

生成物 1

HCID 144014008-(Trichlorosilyl)octyl 2-methylprop-2-enoate

試薬・触媒・溶媒 2

HCID 73357391Platinum(4+);tetrachloride;hexahydrate触媒HCID 8028Tetrahydrofuran
溶媒

反応条件

温度
40 °C

実験手順

A reaction vessel fitted with a stirrer was charged with 50 g of 7-octenyl methacrylate, 250 mg of hydroquinone monomethyl ether and 1.5 cc of 1% chloroplatinic acid hexahydrate solution in tetrahydrofuran, and the mixture was heated to 40° C. To the mixture was added gradually 42 g of trichlorosilane with stirring, while the temperature of the mixture was kept at 45° C. or below. After the addition, the mixture was heated to 60° C. and reaction was conducted at this temperature for 1 hour to obtain 8-methacryloyloxyoctyltrichlorosilane.

後処理

  1. customA reaction vessel fitted with a stirrer
  2. customwas kept at 45° C. or below
  3. additionAfter the addition
  4. temperaturethe mixture was heated to 60° C.
  5. customreaction

出典と根拠

ORDレコード
ord-dd7bc112b5864f298b297fa5053c8830
出典データセット
uspto-grants-1993_03
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US05192815

反応ノート

読み込み中…

このページの内容参加物反応条件実験手順後処理出典と根拠反応ノート