Dimethyloctadecylamine → N-(2-(Benzoyloxy)ethyl)-N,N-dimethyl-n-octadecylammonium bromide

HRID 1613701

反応式

HRID 1613701 の反応式
[C:1]([O:9][CH2:10][CH2:11][Br:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:13][N:14]([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])[CH3:15]>C(#N)C>[Br-:12].[C:1]([O:9][CH2:10][CH2:11][N+:14]([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])([CH3:13])[CH3:15])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

4

反応物 2

HCID 15365DimethyloctadecylamineHCID 5230902-Bromoethyl Benzoate

生成物 1

HCID 19774320N-(2-(Benzoyloxy)ethyl)-N,N-dimethyl-n-octadecylammonium bromide

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

A mixture of 45.0 g (0.1964 mol) of 2-bromoethyl benzoate and an equimolar amount of N,N-dimethyl-n-octadecylamine in 207 ml of acetonitrile was heated at reflux for 4.5 hours. The reaction mixture was then cooled. The solid was then collected, washed with ether, and dried to yield 76.7 g of the title compound; mp=87°-93° C.

後処理

  1. temperatureat reflux for 4.5 hours
  2. temperatureThe reaction mixture was then cooled
  3. customThe solid was then collected
  4. washwashed with ether
  5. customdried

出典と根拠

ORDレコード
ord-5d30a4eeed0a41b5be19d5faad877ab9
出典データセット
uspto-grants-1993_03
特許番号
US05194472

関連ノート

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