Ethanol → Zinc hexadecyl phosphate

HRID 1614138

反応式

HRID 1614138 の反応式
[CH2:1]([O:17][P:18](=[O:21])([OH:20])[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].C(O)C.[OH-].[Na+].O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Zn+2:39]>O>[CH2:1]([O:17][P:18]([O-:21])([O-:20])=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[Zn+2:39]

参加物

6

反応物 4

HCID 702EthanolHCID 14798Sodium Hydroxide2 回HCID 19059Hexadecyl phosphateHCID 62640Zinc Sulfate Heptahydrate

生成物 1

HCID 11970389Zinc hexadecyl phosphate

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

50 g of monocetylphosphoric acid and 100 g of ethanol were put into a 500 ml reaction vessel. Further, a solution of 6.29 g of 96% sodium hydroxide (purity was taken into consideration by calculating it from the degree of neutralization determined by titration) dissolved in 200 g of ion-exchanged water was added thereto. After the temperature was elevated to 80° C., it was confirmed that they were clearly dissolved. The solution was continuously stirred for 30 minutes. A solution of 22.3 g of zinc sulfate heptahydrate dissolved in 100 g of ion-exchanged water was added dropwise thereto to carry out a salt exchange reaction. After the completion of the addition, the mixture was stirred for 30 minutes. 13.20 g of an aqueous solution of 33.33% sodium hydroxide was added dropwise thereto to adjust the pH of the reaction mixture to 6.6. Further, the mixture was continuously stirred for one hour. After the completion of the reaction, the mixture was cooled and the product was collected by filtration, washed with water and dried, to obtain 49.3 g of the particles of zinc monocetylphosphate (zinc/sodium/phosphorus=0.77/1.42/2.00).

後処理

  1. additionwas added
  2. customwas elevated to 80° C.
  3. dissolutionwere clearly dissolved
  4. additionwas added dropwise
  5. customa salt exchange reaction
  6. additionAfter the completion of the addition
  7. stirringthe mixture was stirred for 30 minutes
  8. stirringFurther, the mixture was continuously stirred for one hour
  9. customAfter the completion of the reaction
  10. temperaturethe mixture was cooled
  11. filtrationthe product was collected by filtration
  12. washwashed with water
  13. customdried

出典と根拠

ORDレコード
ord-ec2aed2d2eba47169618d64627b2be19
出典データセット
uspto-grants-1993_03
特許番号
US05196186

関連ノート

読み込み中…