Benzoyl Peroxide → 1,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

HRID 1614803ノート

反応式

HRID 1614803 の反応式
[C:1]1([C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:8][CH3:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:34]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:34][CH2:9][CH:8]=[C:7]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

5

反応物 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2382071,1-Diphenyl-1-propene

生成物 1

HCID 123465451,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

A mixture of 1,1-diphenyl-1-propene (17.0 g, 0.10 mol), carbon tetrachloride (100 ml), benzoylperoxide (0.2 g) and N-bromosuccinimide (17.8 g, 0.10 mol) was heated at reflux temperature for 18 h. The reaction mixture was allowed to cool to room temperature, filtered and the solvent was evaporated in vacuo to give 3-bromo-1 1-diphenyl-1-propene in a quantitative yield.

後処理

  1. temperaturewas heated
  2. temperatureat reflux temperature for 18 h
  3. filtrationfiltered
  4. customthe solvent was evaporated in vacuo

出典と根拠

ORDレコード
ord-49284c1892f1468eab03279d1f3b0fe0
出典データセット
uspto-grants-1993_03
特許番号
US05198451

反応ノート

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