Phenol → Sodium phenoxide

HRID 1616950

反応式

HRID 1616950 の反応式
[CH2:1]([OH:13])[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:14]1([OH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Na:21]>C1(C)C=CC=CC=1>[Na:21].[CH2:1]([OH:13])[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Na:21].[C:14]1([OH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

参加物

6

反応物 3

HCID 996PhenolHCID 907332-Dodecen-1-olHCID 5360545Sodium

生成物 2

HCID 66602278Sodium phenoxideHCID 867166002-Dodecen-1-ol sodium salt

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
60 °C

実験手順

Into a 5-liter flask equipped with a reflux condenser, a thermometer, and a stirrer, 3,500 mL of toluene is weighed and put, and 1141 g (6.2 mol) of 2-dodecen-1-ol and 583 g (6.2 mol) of phenol are added thereto, followed by stirring until homogeneous. 74 g (3.2 gram atom) of metallic sodium is introduced thereto at 50° C. or lower, followed by warming to 60° C. over 1 hour after the completion of the introduction, and then stirring at from 60° C. to 68° C. for 4 hours to obtain a solution of 2-dodecen-1-ol sodium salt and phenol sodium salt.

後処理

  1. customInto a 5-liter flask equipped with a reflux condenser
  2. customat 50° C.
  3. stirringstirring at from 60° C. to 68° C. for 4 hours

出典と根拠

ORDレコード
ord-213457bd0a4b48b8bbd6aca71cbd0da3
出典データセット
uspto-grants-2014_07
特許番号
US08765878B2

関連ノート

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