4-Ethenylphenyl acetate → Propylene glycol methyl ether acetate

HRID 1618839

反応式

HRID 1618839 の反応式
[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9]([CH:12]=[CH2:13])=[CH:8][CH:7]=1)[CH:2]1[O:4][CH2:3]1.[C:14]([O:19][CH:20]([O:22][CH2:23][CH3:24])[CH3:21])(=[O:18])[C:15]([CH3:17])=[CH2:16].[C:25]([O:28][C:29]1[CH:36]=[CH:35][C:32]([CH:33]=[CH2:34])=[CH:31][CH:30]=1)(=[O:27])[CH3:26].N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>CCCCCCC.C(C(C)=O)C(C)C>[C:20]([O:22][CH:23]([CH3:24])[CH2:3][O:4][CH3:2])(=[O:19])[CH3:21].[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9]([CH:12]=[CH2:13])=[CH:8][CH:7]=1)[CH:2]1[O:4][CH2:3]1.[C:14]([O:19][CH:20]([O:22][CH2:23][CH3:24])[CH3:21])(=[O:18])[C:15]([CH3:17])=[CH2:16].[C:25]([O:28][C:29]1[CH:36]=[CH:35][C:32]([CH:33]=[CH2:34])=[CH:31][CH:30]=1)(=[O:27])[CH3:26]

参加物

8

反応物 4

HCID 758214-Ethenylphenyl acetateHCID 1028652-((4-Ethenylphenoxy)methyl)oxiraneHCID 201933451-Ethoxyethyl Methacrylate (stabilized with MEHQ)HCID 219175032,2'-Azobis(methyl 2-methylpropanate)

生成物 2

HCID 7946Propylene glycol methyl ether acetateHCID 86655547p-Vinylphenyl glycidyl ether 1-ethoxyethyl methacrylate p-acetoxystyrene

試薬・触媒・溶媒 2

HCID 7909Methyl Isobutyl Ketone溶媒HCID 8900Heptane溶媒

実験手順

A 500 ml three-necked flask was charged with 52.9 g (0.30 mol) of p-vinylphenyl glycidyl ether, 19.0 g (0.12 mol) of 1-ethoxyethyl methacrylate, 29.2 g (0.18 mol) of p-acetoxystyrene and 300 ml of methyl isobutyl ketone. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) as a radical polymerization initiator was added to the mixture, and polymerization was performed in a nitrogen stream at 80° C. for six hours. The obtained reaction liquid was cooled, and poured in a large volume of heptane, thereby precipitating a polymer. The polymer crystal was collected by filtration, and dissolved in propylene glycol monomethyl ether acetate. The heptane and methyl isobutyl ketone contained in the solution were distilled off in vacuum, thereby obtaining a propylene glycol monomethyl ether acetate solution of polymer A2-4 (p-vinylphenyl glycidyl ether/1-ethoxyethyl methacrylate/p-acetoxystyrene).

後処理

  1. customThe obtained reaction liquid
  2. temperaturewas cooled
  3. customprecipitating a polymer
  4. filtrationThe polymer crystal was collected by filtration
  5. dissolutiondissolved in propylene glycol monomethyl ether acetate
  6. distillationwere distilled off in vacuum

出典と根拠

ORDレコード
ord-4798a565f1ce45ff99b8e86aba68706b
出典データセット
uspto-grants-2014_07
特許番号
US08771907B2

関連ノート

読み込み中…